{"id":4394,"date":"2023-03-20T02:25:50","date_gmt":"2023-03-19T17:25:50","guid":{"rendered":"https:\/\/www.pirika.com\/wp\/%e8%a1%a8%e9%9d%a2%e5%bc%b5%e5%8a%9b%e3%81%ae%e7%90%86%e8%a7%a3%e3%81%ae%e3%81%9f%e3%82%81%e3%81%ab"},"modified":"2024-09-27T22:37:58","modified_gmt":"2024-09-27T13:37:58","slug":"surfacetension2","status":"publish","type":"page","link":"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/surfacetension2","title":{"rendered":"\u8868\u9762\u5f35\u529b\u306e\u7406\u89e3\u306e\u305f\u3081\u306b"},"content":{"rendered":"\n<link rel=\"stylesheet\" href=\"https:\/\/www.pirika.com\/Images20\/TT.css\">\n<link rel=\"stylesheet\" href=\"https:\/\/www.pirika.com\/Images20\/title.css\">\n\n<p align=\"right\">2013.8.16<\/p>\n\n<iframe src=\"https:\/\/www.pirika.com\/title.html\" width=\"100%\" id=\"inner-flame\"><\/iframe>\n\n\n\n<h2 class=\"wp-block-heading\"><a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\">\u7269\u6027\u5316\u5b66\u30c8\u30c3\u30d7\u30da\u30fc\u30b8<\/a><\/h2>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\u306e\u63a8\u7b97\u6cd5\u3082<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/st-theory\">\u53c2\u7167\u3057\u3066\u304f\u3060\u3055\u3044<\/a>\u3002<br>\u6b21\u4e16\u4ee3HSP\u6280\u8853\u3001<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/hsp\/examples\/docs\/hsp-surten\">HSP\u3068\u8868\u9762\u5f35\u529b<\/a>\u3092\u53c2\u7167\u3057\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\uff08\u3072\u3087\u3046\u3081\u3093\u3061\u3087\u3046\u308a\u3087\u304f\u3001\u82f1\u8a9e: surface tension\uff09\u306f\u3001\u8868\u9762\u3092\u3067\u304d\u308b\u3060\u3051\u5c0f\u3055\u304f\u3057\u3088\u3046\u3068\u3059\u308b\u50be\u5411\u3092\u6301\u3064\u6db2\u4f53\u306e\u6027\u8cea\u3001\u307e\u305f\u305d\u306e\u529b\u306e\u3053\u3068\u3067\u3001\u754c\u9762\u5f35\u529b\u306e\u4e00\u7a2e\u3067\u3042\u308b\u3002<br>\u6b63\u78ba\u306a\u5b9a\u7fa9\u3092\u8a00\u3046\u306a\u3089\u3070\u3001\u6db2\u4f53\u8868\u9762\u306e\u6301\u3064\u3001\u5185\u90e8\u306b\u6bd4\u3079\u3066\u4f59\u5270\u306a\u5358\u4f4d\u9762\u7a4d\u5f53\u305f\u308a\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3067\u3042\u308b\u3002<br>\u6db2\u4f53\u8868\u9762\u304c\u5c0f\u3055\u304f\u306a\u308d\u3046\u3068\u3059\u308b\u306e\u306f\u3001\u71b1\u529b\u5b66\u7b2c\u4e8c\u6cd5\u5247\u3088\u308a\u30ae\u30d6\u30ba\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u5c0f\u3055\u3044\u72b6\u614b\u306f\u5b89\u5b9a\u3059\u308b\u305f\u3081\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5927\u304d\u3044\u8868\u9762\u5206\u5b50\u304c\u5c0f\u3055\u3044\u5185\u90e8\u5206\u5b50\u306b\u7f6e\u304d\u63db\u308f\u308d\u3046\u3068\u3059\u308b\u305f\u3081\u3067\u3042\u308b\u3002(WikiPedia)<\/p>\n\n\n\n<p>\u3042\u308b\u6db2\u4f53\uff08\u70ad\u7d20\u6570\uff14\uff09\u304c\u3042\u3063\u305f\u3068\u304d\u306b\u3001\u3053\u308c\u3089\u306e\u6db2\u4f53\u306e25\u2103\u3067\u306e\u8868\u9762\u5f35\u529b\u306e\u5024\u306b\u3088\u3063\u3066\u4e26\u3073\u66ff\u3048\u308b\u4e8b\u304c\u3067\u304d\u308b\u3060\u308d\u3046\u304b\uff1f<br>\u305d\u308c\u3092\u3057\u3088\u3046\u3068\u601d\u3063\u305f\u3068\u304d\u3001\u5316\u5408\u7269\u306e\u3069\u3093\u306a\u6307\u6a19\u3092\u4f7f\u304a\u3046\u3068\u601d\u3046\u3060\u308d\u3046\u304b\uff1f<\/p>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td>Hcode<\/td><td>Liquid<\/td><\/tr><tr><td>92<\/td><td>n-Butanol<\/td><\/tr><tr><td>255<\/td><td>Ehtyl ether<\/td><\/tr><tr><td>1060<\/td><td>n-Butylaldehyde<\/td><\/tr><tr><td>481<\/td><td>Methyl ethyl ketone<\/td><\/tr><tr><td>116<\/td><td>Butyronitrile<\/td><\/tr><tr><td>114<\/td><td>n-Butylic acid<\/td><\/tr><tr><td>328<\/td><td>Ethyl acetate<\/td><\/tr><tr><td>285<\/td><td>N,N-Dimethylacetoamide<\/td><\/tr><tr><td>260<\/td><td>Diethyl sulfide<\/td><\/tr><tr><td>91<\/td><td>1-Butanethiol<\/td><\/tr><tr><td>105<\/td><td>n-Butyl amine<\/td><\/tr><tr><td>252<\/td><td>Diethyl amine<\/td><\/tr><tr><td>81<\/td><td>1,3-Butadiene<\/td><\/tr><tr><td>1154<\/td><td>Decafluorobutane<\/td><\/tr><tr><td>152<\/td><td>1-Chlorobutane<\/td><\/tr><tr><td>3670<\/td><td>1-Bromobutane<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<p>\u6211\u3005\u306f\u6cb9\u306f\u6c34\u306b\u6d6e\u304f\u4e8b\u3092\u77e5\u3063\u3066\u3044\u308b\u3002\u305d\u308c\u306f\u3001\u6c34\u3068\u6cb9\u304c\u6df7\u3058\u3089\u305a\u3001\u6cb9\u306e\u6bd4\u91cd\u304c\u6c34\u3088\u308a\u8efd\u3044\u304b\u3089\u3067\u3042\u308b\u3002<br>\u3057\u304b\u3057\u3001\u6bd4\u91cd\u304c\u6c34\u3088\u308a\u3082\u91cd\u3044\uff11\u5186\u7389\u304c\u8868\u9762\u5f35\u529b\u306b\u3088\u3063\u3066\u6c34\u306e\u4e0a\u306b\u6d6e\u304b\u3076\u4e8b\u3082\u77e5\u3063\u3066\u3044\u308b\u3002<br>\u305d\u3057\u3066\u3001\u6c34\u306f\u975e\u5e38\u306b\u5927\u304d\u306a\u8868\u9762\u5f35\u529b\u3092\u6301\u3064\u4e8b\u3082\u77e5\u3063\u3066\u3044\u308b\u306e\u3067\u3001\u4e0a\u306e\u8868\u306e\u3088\u3046\u306a\u5316\u5408\u7269\u304c\u3042\u3063\u305f\u6642\u306b\u3001\u6c34\u6eb6\u6027\u306e\u5316\u5408\u7269\u306f\u5927\u304d\u306a\u8868\u9762\u5f35\u529b\u3092\u6301\u3063\u3066\u3044\u308b\u3068\u8003\u3048\u304c\u3061\u3067\u3042\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST01.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\u3057\u304b\u3057\u3001\u8868\u9762\u5f35\u529b\u3068\u6c34\u3078\u306e\u6eb6\u89e3\u5ea6\u306e\u5bfe\u6570\u3092\u56f3\u793a\u3059\u308b\u3068\u4e0a\u56f3\u306e\u3088\u3046\u306b\u3053\u306e\u8003\u3048\u65b9\u306f\u9593\u9055\u3063\u3066\u3044\u308b\u4e8b\u304c\u3059\u3050\u306b\u308f\u304b\u308b\u3002<\/p>\n\n\n\n<p>\u6c34\u3078\u306e\u6eb6\u89e3\u5ea6\u4ee5\u5916\u306b\u306f\u3001\u30c0\u30a4\u30dd\u30fc\u30eb\u30e2\u30fc\u30e1\u30f3\u30c8\u3084\u3001\u8a98\u96fb\u7387\u304b\u3089\u8868\u9762\u5f35\u529b\u3092\u4e26\u3073\u66ff\u3048\u3088\u3046\u3068\u8003\u3048\u308b\u304b\u3082\u3057\u308c\u306a\u3044\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST02.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST03.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\u304a\u304a\u307e\u304b\u306a\u50be\u5411\u306f\u6b63\u3057\u3044\u304c\u3001\u9806\u4f4d\u4ed8\u3051\u3067\u304d\u308b\u307b\u3069\u306e\u7cbe\u5ea6\u304c\u7121\u3044\u4e8b\u3082\u308f\u304b\u308b\u3002<\/p>\n\n\n\n<p>\u305d\u3053\u3067\u3001\u6c34\u6eb6\u6027\u3001\u30c0\u30a4\u30dd\u30fc\u30eb\u30e2\u30fc\u30e1\u30f3\u30c8\u3001\u8a98\u96fb\u7387\u3092\u3054\u3061\u3083\u6df7\u305c\u306b\u3057\u3066\u3001\u201c\u89aa\u6c34\u6027\u201d\u3001\u201c\u89aa\u6cb9\u6027\u201d\u3068\u3044\u3046\u66d6\u6627\u306a\u8a00\u8449\u3067\u304a\u8336\u3092\u6fc1\u3059\u4e8b\u3092\u3059\u308b\u3002<\/p>\n\n\n\n<p>\u201c\u89aa\u6c34\u6027\u201d\u5316\u5408\u7269\u306f\u8868\u9762\u5f35\u529b\u304c\u9ad8\u304f\u3001\u201c\u89aa\u6cb9\u6027\u201d\u5316\u5408\u7269\u306f\u8868\u9762\u5f35\u529b\u304c\u4f4e\u3044\u3002\u3053\u308c\u306f\u6b63\u3057\u3044\u306e\u3060\u308d\u3046\u304b\uff1f<\/p>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\u306e\u6e29\u5ea6\u4f9d\u5b58\u6027\u3092\u56f3\u793a\u3059\u308b\u3068\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u306a\u308a\u3001\u201c\u89aa\u6c34\u6027\u201d\u306e\u30a2\u30df\u30c9\u3084\u30a2\u30eb\u30b3\u30fc\u30eb\u304c\u4e0a\u306b\u304d\u3066\u3001\u30a8\u30fc\u30c6\u30eb\u306a\u3069\u306e\u89aa\u6cb9\u6027\u201d\u5316\u5408\u7269\u304c\u4e0b\u306b\u6765\u308b\u306e\u3067\u6b63\u3057\u3044\u3088\u3046\u306b\u3082\u898b\u3048\u308b\u3002<\/p>\n\n\n\n<p>\u554f\u984c\u306f\u201c\u89aa\u6c34\u6027\u201d\u3001\u201c\u89aa\u6cb9\u6027\u201d\u3068\u3044\u3046\u8a00\u8449\u306e\u5b9a\u7fa9\u3060\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST04.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\u4f8b\u3048\u3070\u30a2\u30df\u30f3\u3092\u89aa\u6c34\u6027\u306e\u5b98\u80fd\u57fa\u3068\u8a8d\u3081\u305f\u3068\u3057\u3066\u3082\u3001\u30b8\u30a8\u30c1\u30eb\u30a2\u30df\u30f3\u3001\u30d4\u30ed\u30ea\u30b8\u30f3\u3001\u30d4\u30ed\u30fc\u30eb\u306e\u8868\u9762\u5f35\u529b\u306e\u9055\u3044\u3092\u3069\u3046\u3059\u308c\u3070\u8aac\u660e\u3067\u304d\u308b\u306e\u3060\u308d\u3046\u304b\uff1f<\/p>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td>Diethyl amine<\/td><td>Pyrrolidine<\/td><td>Pyrrole<\/td><\/tr><tr><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image002_0003.png\" alt=\"\" width=\"140\" height=\"49\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image004_0000.png\" alt=\"\" width=\"50\" height=\"82\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image006_0000.png\" alt=\"\" width=\"41\" height=\"66\"><\/td><\/tr><tr><td>\u03b3=20.05<\/td><td>\u03b3=29.65<\/td><td>\u03b3=37.6<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<p>\u9396\u72b6\u306eNH\u3068\u6bd4\u3079\u3001\u74b0\u72b6\u306eNH\u306f\u89aa\u6c34\u6027\u304c\u9ad8\u304f\u3001\u4e8c\u91cd\u7d50\u5408\u306e\u96a3\u306b\u3042\u308bNH\u306f\u66f4\u306b\u89aa\u6c34\u6027\u304c\u9ad8\u3044\u3002<br>\u3044\u3063\u305f\u3044\u5e7e\u3064\u306eNH\u3092\u5b9a\u7fa9\u3057\u305f\u3089\u5168\u3066\u306eNH\u3092\u8868\u3059\u4e8b\u304c\u3067\u304d\u308b\u306e\u3060\u308d\u3046\u304b\uff1f<br>\u8868\u9762\u5f35\u529b\u306e\u63a8\u7b97\u5f0f\u3068\u3057\u3066\u6700\u3082\u8457\u540d\u306a<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/st-theory\">Macleod-Sudgen\u5f0f<\/a>\u3067\u306f\u3001Sudgen\u306f\u5b9f\u969b\u306b\u6b21\u306e\u3088\u3046\u306a\u30d1\u30e9\u30b3\u30fc\u30eb\u3092\u5b9a\u7fa9\u3057\u3066\u3044\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST05.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\uff08\u4e95\u672c\u7a14\u3001\u8868\u9762\u5f35\u529b\u306e\u7406\u89e3\u306e\u305f\u3081\u306b\u3001\u9ad8\u5206\u5b50\u520a\u884c\u4f1a\u30011993\uff09<br><br>\u74b0\u3084\uff12\u91cd\u7d50\u5408\u306b\u88dc\u6b63\u5024\u3092\u5165\u308c\u306a\u3044\u3068\u63a8\u7b97\u5f0f\u306e\u7cbe\u5ea6\u304c\u4e0a\u304c\u3089\u306a\u3044\u4e8b\u306f\u30011924\u5e74\u306eSudgen\u306e\u8ad6\u6587\u306e\u6642\u304b\u3089\u8a8d\u8b58\u3055\u308c\u3066\u3044\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td>Ehtyl ether<\/td><td>Tetrahydrofuran<\/td><td colspan=\"2\">Furan<\/td><\/tr><tr><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image002_0004.png\" alt=\"\" width=\"140\" height=\"27\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image004_0001.png\" alt=\"\" width=\"41\" height=\"44\"><\/td><td colspan=\"2\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image006_0001.png\" alt=\"\" width=\"51\" height=\"52\"><\/td><\/tr><tr><td>\u03b3=17.06<\/td><td>\u03b3=27.2<\/td><td colspan=\"2\">\u03b3=24.1<\/td><\/tr><tr><td>Diethyl sulfide<\/td><td>Tetrahydrothiophene<\/td><td>Thiophene<\/td><td>&nbsp;<\/td><\/tr><tr><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image008_0000.png\" alt=\"\" width=\"143\" height=\"29\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image010_0000.png\" alt=\"\" width=\"51\" height=\"53\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image012.png\" alt=\"\" width=\"50\" height=\"53\"><\/td><td>&nbsp;<\/td><\/tr><tr><td>\u03b3=25.2<\/td><td>\u03b3=35.8<\/td><td>\u03b3=32.8<\/td><td>&nbsp;<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<p>\u3068\u3053\u308d\u304c\u3001\u30a8\u30fc\u30c6\u30eb\u9178\u7d20\u3084\u30c1\u30aa\u30a8\u30fc\u30c6\u30eb\u3067\u306f\u3001\u74b0\u72b6\u306b\u306a\u308b\u52b9\u679c\u306f\u540c\u3058\u3060\u304c\u3001\uff12\u91cd\u7d50\u5408\u306e\u52b9\u679c\u306f\u30a2\u30df\u30f3\u3068\u306f\u540c\u3058\u3067\u306f\u306a\u3044\u3002<\/p>\n\n\n\n<p>\u3055\u3089\u306b\u3001\u5206\u5b50\u306e\u5f62\u72b6\u306e\u52b9\u679c\u3082\u3042\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td><br>n-Butanol<\/td><td>2-Butanol<\/td><td>i-Butanol<\/td><td>t-Butanol<\/td><\/tr><tr><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image014.png\" alt=\"\" width=\"94\" height=\"94\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image016.png\" alt=\"\" width=\"100\" height=\"47\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image018.png\" alt=\"\" width=\"79\" height=\"77\"><\/td><td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/clip_image020.png\" alt=\"\" width=\"79\" height=\"77\"><\/td><\/tr><tr><td>\u03b3=24.52<\/td><td>\u03b3=23<\/td><td>\u03b3=23<\/td><td>\u03b3= 19.56<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<p>\u5206\u5b50\u304c\u7403\u5f62\u306b\u8fd1\u3065\u304f\u306b\u3064\u308c\u3001\u8868\u9762\u5f35\u529b\u306f\u4f4e\u4e0b\u3059\u308b\u3002<\/p>\n\n\n\n<p>Beerbower (1971) \u306f\u8868\u9762\u5f35\u529b\u306e\u63a8\u7b97\u306b\u4e0b\u5f0f\u3092\u63d0\u6848\u3057\u3066\u3044\u308b\u3002<\/p>\n\n\n\n<p>\u03b3=0.0715*MVol<sup>1\/3<\/sup> [dD<sup>2<\/sup> +0.632*(dP<sup>2<\/sup> + dH<sup>2<\/sup> )]<\/p>\n\n\n\n<p>dD, dP, dH\u306f<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/hsp\">\u30cf\u30f3\u30bb\u30f3\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf<\/a>\u3002<\/p>\n\n\n\n<p>\u86c7\u8db3\u3067\u306f\u3042\u308b\u304c\u3001\u81ea\u5206\u306f<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/hsp\/hspip\/hspip-abs\">\u30cf\u30f3\u30bb\u30f3\u5148\u751f\u3068\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf<\/a>\u306e\u4ed5\u4e8b\u3092\u3057\u3066\u3044\u308b\u3002\u3000<br>\u4eca\u5e74(2013)\u30c7\u30f3\u30de\u30fc\u30af\u306e\u30cf\u30f3\u30bb\u30f3\u5148\u751f\u306e\u3054\u81ea\u5b85\u3067\u69d8\u3005\u306a\u6253\u3061\u5408\u308f\u305b\u3092\u884c\u3063\u305f\u969b\u3001\u30cf\u30f3\u30bb\u30f3\u5148\u751f\u304b\u3089\u6559\u3048\u3066\u3044\u305f\u3060\u3044\u305f\u306e\u3060\u304c\u3001\u81ea\u5206(Hansen\u5148\u751f)\u306f\u3053\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\u3092\u30cf\u30f3\u30bb\u30f3\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\u3068\u547c\u3093\u3060\u4e8b\u306f\u7121\u3044\u3002\u30cf\u30f3\u30bb\u30f3\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\uff1aHSP\u3068\u3044\u3046\u306e\u306fBeerbower\u6559\u6388\u304c\u540d\u4ed8\u3051\u305f\u306e\u3060\u3068\u3002<br>\u3061\u306a\u307f\u306b\u524d\u51fa\u306e\u4e95\u672c\u7a14\u5148\u751f\u306e\u66f8\u7c4d\u3067\u306f\u3001Beerbower\u304cBeerwober\u306b\u306a\u3063\u3066\u3044\u308b\u304c\u3001\u9593\u9055\u3044\u3067\u3042\u308b\u3002<\/p>\n\n\n\n<p>\u3053\u306e\u5f0f\u3092\u8a55\u4fa1\u3057\u3066\u307f\u305f\u3068\u3053\u308d\u3001\u5206\u5b50\u304c\u3042\u308b\u7a0b\u5ea6\u5927\u304d\u3044\u5834\u5408\u306b\u306f\u3001\u975e\u5e38\u306b\u7cbe\u5ea6\u3088\u304f\u63a8\u7b97\u3067\u304d\u3066\u3044\u308b\u4e8b\u304c\u5224\u3063\u305f\u3002\u3057\u304b\u3057\u3001\u3053\u306e\u5f0f\u3092C4\u306e\u5316\u5408\u7269\u306b\u9069\u7528\u3057\u305f\u3068\u3053\u308d\u7279\u306b\u30a2\u30eb\u30b3\u30fc\u30eb\u3067\u5927\u304d\u306a\u8aa4\u5dee\u306b\u306a\u3063\u3066\u3057\u307e\u3046\u4e8b\u3082\u660e\u3089\u304b\u306b\u306a\u3063\u305f\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST06.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u305d\u308c\u306b\u3057\u3066\u3082\u3001\u8868\u9762\u5f35\u529b\u3092\u898b\u7a4d\u3082\u308b\u6307\u6a19\u3068\u3057\u3066\u3001\u6700\u3082\u512a\u308c\u3066\u3044\u308b\u306e\u30cf\u30f3\u30bb\u30f3\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\uff08HSP\uff09\u3067\u3042\u308b\u3068\u8a00\u3048\u308b\u3002\u30a2\u30eb\u30b3\u30fc\u30eb\u985e\u306e\u7570\u5e38\u306f\u6c34\u7d20\u7d50\u5408\u306b\u3088\u308b\u3082\u306e\u3068\u8003\u3048\u308b\u304b\u3082\u3057\u308c\u306a\u3044\u304c\u3001n-butylic acid\u306f\u4f8b\u5916\u306b\u306a\u3089\u306a\u3044\u306e\u3067\u6c34\u7d20\u7d50\u5408\u306b\u3088\u308b\u3082\u306e\u3067\u306f\u306a\u3044\u3002<\/p>\n\n\n\n<p>HSP\u306e\u304a\u304a\u3082\u3068\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u306f<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/hv-theory\">\u84b8\u767a\u6f5c\u71b1(Hv)<\/a>\u3067\u3042\u308b\u3002<br>Total HSP = SQRT ((Hv-RT)\/MVol)<br>(R: \u30ac\u30b9\u5b9a\u6570, MVol: \u5206\u5b50\u4f53\u7a4d)<\/p>\n\n\n\n<p>\u84b8\u767a\u6f5c\u71b1\u306e\u5b9f\u6e2c\u3067\u306f\u3001\u6cb8\u70b9\u306b\u304a\u3051\u308b\u6e2c\u5b9a\u304c\u6700\u3082\u5b89\u5b9a\uff08\u5e38\u5727\u3067\u306f\u6cb8\u70b9\u3067\u306f\u6e29\u5ea6\u304c\u5909\u5316\u3057\u306a\u3044\uff09\u3067\u3042\u308b\u306e\u3067\u3001\u6cb8\u70b9\u306b\u304a\u3051\u308b\u84b8\u767a\u6f5c\u71b1\u306e\u5024\u304c\u6700\u3082\u7cbe\u5ea6\u304c\u9ad8\u3044\u3002\u3057\u304b\u3057\u3001HSP\u3067\u306f25\u2103\u306b\u304a\u3051\u308b\u84b8\u767a\u6f5c\u71b1\u304c\u5fc5\u8981\u306b\u306a\u308b\u3002\u305d\u3053\u3067Watson\u5f0f\u3092\u4f7f\u3063\u3066\u6cb8\u70b9\u306b\u304a\u3051\u308b\u84b8\u767a\u6f5c\u71b1\u309225\u2103\u306b\u5909\u63db\u3059\u308b\u3002<\/p>\n\n\n\n<p>dHv2=dHv1((1-Tr2)\/(1-Tr1))<sup>0.375<\/sup><br>(dHv1: \u6cb8\u70b9\u306b\u304a\u3051\u308b\u84b8\u767a\u6f5c\u71b1, Tr1 : \u6cb8\u70b9 \/ \u81e8\u754c\u6e29\u5ea6, Tr2 : \u4efb\u610f\u306e\u6e29\u5ea6 \/ \u81e8\u754c\u6e29\u5ea6 )<br><br>\u305d\u3053\u3067\u3001\u6cb8\u70b9\u306b\u304a\u3051\u308b\u84b8\u767a\u6f5c\u71b1\u3001\u6cb8\u70b9\u3001<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/tc-theory\">\u81e8\u754c\u6e29\u5ea6<\/a>\u304c\u5224\u308c\u3070\u3001\u4efb\u610f\u306e\u6e29\u5ea6\u3067\u306e\u84b8\u767a\u6f5c\u71b1\u304c\u8a08\u7b97\u3067\u304d\u308b\u3002<\/p>\n\n\n\n<p>\u3053\u306e\u5f0f\u306e\u6307\u6570\u30010.375 \u306f\u3069\u3053\u304b\u3089\u6765\u305f\u306e\u3060\u308d\u3046\u304b\uff1f<br>\u3053\u306e\u5f0f\u306e\u7cbe\u5ea6\u306f\uff1f<br>\u3069\u306e\u3088\u3046\u306a\u5316\u5408\u7269\u306b\u9069\u7528\u3067\u304d\u308b\/\u3067\u304d\u306a\u3044\uff1f<\/p>\n\n\n\n<p>\u3053\u308c\u306b\u3064\u3044\u3066\u306f\u8aac\u660e\u3057\u3066\u304a\u3044\u305f\u65b9\u304c\u3044\u3044\u3060\u308d\u3046\u3002<\/p>\n\n\n\n<p>\u305f\u3068\u3048\u3070\u3001\u3044\u304f\u3064\u304b\u306e\u5316\u5408\u7269\u306b\u3064\u3044\u3066\u3001\u6e29\u5ea6\u306b\u5bfe\u3059\u308b\u84b8\u767a\u6f5c\u71b1\u3092\u30d7\u30ed\u30c3\u30c8\u3059\u308b\u3068\u4e0b\u56f3\u306e\u3088\u3046\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST07.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\u66f2\u7dda\u306f\u5316\u5408\u7269\u3054\u3068\u306b\u7570\u306a\u308b\u3002\u4f8b\u3048\u3070\u3001n-Butanol\u3067\u306f\u3001\u6e29\u5ea6\u304c\u4e0a\u6607\u3059\u308b\u306b\u3064\u308c\u3066\u6c34\u7d20\u7d50\u5408\u304c\u5207\u65ad\u3055\u308c\u3066\u6025\u6fc0\u306b\u84b8\u767a\u6f5c\u71b1\u304c\u5c0f\u3055\u304f\u306a\u308b\u3002\u4ed6\u306e\u66f2\u7dda\u306f\u5927\u4f53\u3001\u5e73\u884c\u95a2\u4fc2\u306b\u3042\u308b\u3002\u305d\u3057\u3066\u81e8\u754c\u70b9\u3067\u306f\u84b8\u767a\u6f5c\u71b1\u306f\uff10\u306b\u306a\u308b\u3002<br>Watson \u5f0f\u306e\u8a00\u3063\u3066\u3044\u308b\u4e8b\u306f\u3001\u3053\u306e\u56f3\u306eX\u8ef8\u3092\u6e29\u5ea6\u304b\u3089\u3001(1-T\/Tc)\u306b\u5909\u3048\u306a\u3055\u3044\u3068\u3044\u3046\u3053\u3068\u3060\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST08.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u3059\u308b\u3068\u539f\u70b9\u3067\u306f\u84b8\u767a\u6f5c\u71b1\u306f\u5168\u3066\u306e\u5316\u5408\u7269\u3067\uff10\u306b\u306a\u308b\u306e\u3067\u3001\u5f0f\u306e\u4e00\u822c\u5316\u304c\u53ef\u80fd\u306b\u306a\u308b\u3002<br><br>\u305d\u3046\u3059\u308b\u3068\u3001\u6c34\u7d20\u7d50\u5408\u6027\u306e\u5316\u5408\u7269\u306f\u5927\u304d\u304f\u5916\u308c\u308b\u304c\u305d\u308c\u4ee5\u5916\u306e\u5316\u5408\u7269\u306e\u66f2\u7dda\u306f\u307b\u307c\u4e00\u5b9a\u306b\u306a\u308b\u3002<br>\u8a66\u3057\u306bdiethyl sulfide\u306e\u66f2\u7dda\u3092\u30ab\u30fc\u30d6\u30fb\u30d5\u30a3\u30c3\u30c8\u3059\u308b\u3068\u6307\u6570\u306e\u4fc2\u6570\u306f0.3528\u306b\u306a\u308b\u3002<br><br>\u3064\u307e\u308a\u3001Watson\u5f0f\u306e\u6307\u6570\u306f\u3001\u5316\u5408\u7269\u3054\u3068\u306e\u6307\u6570\u3092\u5e73\u5747\u3059\u308b\u30680.375\u306b\u306a\u308b\u3068\u8a00\u3063\u3066\u3044\u308b\u4e8b\u306b\u306a\u308b\u3002\u5f93\u3063\u3066Watson\u5f0f\u306f\u6c34\u7d20\u7d50\u5408\u6027\u306e\u5316\u5408\u7269\u306b\u306f\u4f7f\u3048\u306a\u3044\u3002<\/p>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\u3082\u81e8\u754c\u70b9\u3067\u306f\uff10\u306b\u306a\u308b\u3002\u305d\u3053\u3067\u3001Watson\u5f0f\u3068\u540c\u69d8\u3001X\u8ef8\u3092(1-Tref\/Tc)\u3078\u5909\u66f4\u3059\u308b\u306e\u306f\u6709\u52b9\u3060\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST04.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>X\u8ef8\u3092\u5909\u66f4\u3059\u308b\u3068\u4e0b\u56f3\u306e\u3088\u3046\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST09.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u84b8\u767a\u6f5c\u71b1\u306e\u5834\u5408\u3068\u7570\u306a\u308a\u3001\u8868\u9762\u5f35\u529b\u3067\u306f\u6c34\u7d20\u7d50\u5408\u6027\u306e\u5316\u5408\u7269\u3067\u3082\u66f2\u7dda\u306f\u307b\u3068\u3093\u3069\u5b8c\u5168\u306b\u4e00\u81f4\u3059\u308b\u3002<br>\u3053\u306e\u4e8b\u306f\u4f55\u3092\u610f\u5473\u3059\u308b\u304b\u3068\u3044\u3046\u3068\u3001<mark style=\"background-color:#ffef8e\" class=\"has-inline-color has-dark-gray-color\">\u6db2\u4f53\u306e\u8868\u9762\u5f35\u529b\u306fTc\uff08\u81e8\u754c\u6e29\u5ea6\uff09\u306e\u307f\u306b\u3088\u3063\u3066\u6c7a\u307e\u3063\u3066\u3044\u308b<\/mark>\u3068\u3044\u3046\u4e8b\u3060\u3002<br><br>\u8868\u9762\u5f35\u529b\u304c\u9ad8\u3044\u3068\u3044\u3046\u306e\u306f\u3001\u6e2c\u5b9a\u6e29\u5ea6\uff0825\u2103\uff09\u304cTc\u304b\u3089\u9060\u304f\u306f\u306a\u308c\u3066\u3044\u308b\u3060\u3051\u306e\u4e8b\u3060\u3002<br>\u30d5\u30ed\u30f3\u306a\u3069\u306e\u30d5\u30c3\u7d20\u7cfb\u306e\u6eb6\u5a92\u304c\u8868\u9762\u5f35\u529b\u304c\u4f4e\u3044\u306e\u306f\u81e8\u754c\u6e29\u5ea6\u304c\u5ba4\u6e29\u306b\u8fd1\u3044\u3060\u3051\u306e\u4e8b\u3060\u3002<br><br>\u89aa\u6c34\u6027\u201d\u3001\u201c\u89aa\u6cb9\u6027\u201d\u3082\u6c34\u7d20\u7d50\u5408\u3082\u5168\u304f\u95a2\u4fc2\u306a\u3044\uff01<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST10.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>C4\u5316\u5408\u7269\u306e\u8868\u9762\u5f35\u529b\u3092(1-Tref\/Tc)\u306b\u5bfe\u3057\u3066\u30d7\u30ed\u30c3\u30c8\u3059\u308b\u3068\u4e0a\u56f3\u306e\u3088\u3046\u306b\u304d\u308c\u3044\u306a\u76f8\u95a2\u304c\u5f97\u3089\u308c\u308b\u3002<br>\u539f\u5b50\u3054\u3068\u306e\u52b9\u679c\u304c\u30ad\u30e3\u30f3\u30bb\u30eb\u3055\u308c\u305f\u306e\u3067\u3001\u5206\u5b50\u306e\u5f62\u72b6\u56e0\u5b50\u306e\u52b9\u679c\u3092\u898b\u3066\u307f\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewSt11.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u8868\u9762\u5f35\u529b\u306bOvality\u3092\u304b\u3051\u3066\u3042\u3052\u308b\u3068\u3001\u3055\u3089\u306b\u7cbe\u5ea6\u304c\u4e0a\u304c\u308b\u4e8b\u304c\u4e0a\u56f3\u304b\u3089\u5224\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/EACN2.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>Beerbower \u306e\u8ad6\u6587\u306b\u306f (1971), \u3055\u3089\u306b\u9762\u767d\u3044\u5f0f\u304c\u66f8\u304b\u308c\u3066\u3044\u308b\u3002<\/p>\n\n\n\n<p>d (ln \u03b3)\/dT = -4.0 * \u03b1<br>\u03b1: Thermal expansivity<\/p>\n\n\n\n<p>\u3053\u306e\u5f0f\u306f Macleod \u2013 Sudgen \u5f0f\u304b\u3089\u5c0e\u51fa\u3055\u308c\u308b\u3002<\/p>\n\n\n\n<p>\u03b3= (P*(\u03c1-d)\/M)<sup>4<\/sup><br>P: parachor, \u03c1: density of liquid, d: density of Gas, M: molecular weight<\/p>\n\n\n\n<p>\u3053\u3053\u3067\u6c17\u4f53\u306e\u5bc6\u5ea6\u3092\uff10\u3068\u3059\u308b\u3068\u6b21\u306e\u3088\u3046\u306b\u5909\u5f62\u3067\u304d\u308b\u3002<br>\u03b3= (P\/V)<sup>4<\/sup><br>ln\u03b3= 4<em>ln(P) \u2013 4<\/em>ln(V)<\/p>\n\n\n\n<p>\u3082\u3057\u3001Parachor\u304c\u6e29\u5ea6\u4f9d\u5b58\u6027\u306e\u7121\u3044\u7269\u6027\u5024\u3067\u3042\u308b\u306a\u3089\u3001\u5f0f\u306e\u6e29\u5ea6\u5fae\u5206\u306f\u6b21\u306e\u3088\u3046\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<p>d (ln \u03b3)\/dT = -4.0 * d ln(V)\/dT<\/p>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\u306e\u6e29\u5ea6\u5fae\u5206\u306f\u5206\u5b50\u4f53\u7a4d\u306e\u6e29\u5ea6\u5fae\u5206\u3068\u76f8\u95a2\u304c\u3042\u308b\u3053\u3068\u306b\u306a\u308b\u3002\u3053\u3046\u3057\u305f\u95a2\u4fc2\u306f<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/chemeng\/marangoni\">\u30de\u30e9\u30f3\u30b4\u30cb\u6570\u3092\u63a8\u7b97<\/a>\u3059\u308b\u5834\u5408\u306b\u8868\u9762\u5f35\u529b\u306e\u6e29\u5ea6\u5fae\u5206\u304c\u5fc5\u8981\u306a\u306e\u3067\u91cd\u8981\u306a\u5f0f\u3067\u3042\u308b\u3068\u8a00\u3048\u308b\u3002<\/p>\n\n\n\n<p>\u4e0a\u5f0f\u3067\u6e29\u5ea6\u3092\u4f7f\u3046\u3068\u5206\u5b50\u3054\u3068\u306b\u7570\u306a\u3063\u3066\u3057\u307e\u3046\u306e\u3067\u3001(1 \u2013 Tref\/Tc)\u3092\u4f7f\u3044\uff0c\u3053\u306e\u5f0f\u306e\u59a5\u5f53\u6027\u3092\u691c\u8a3c\u3057\u305f\u3002<\/p>\n\n\n\n<p>\u03b3 = 82.106* X<sup>1.5069<\/sup><\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST12.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u540c\u69d8\u306b\u3001\u5206\u5b50\u4f53\u7a4d\u306e\u5f0f\u3092\u4f5c\u308b\u3068\u6b21\u306e\u3088\u3046\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<p>Volume = 77.82 * X<sup>-0.221<\/sup><\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewSt13.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>X\u306e\u524d\u306e\u4fc2\u6570\u300182.106\u306877.82\u306f\u307b\u307c\u540c\u3058\u306a\u306e\u3067\u3001\uff12\u3064\u306e\u5f0f\u304b\u3089\u6b21\u5f0f\u304c\u5f97\u3089\u308c\u308b\u3002<\/p>\n\n\n\n<p>ln \u03b3 = -7.0 * ln Volume + Const.<\/p>\n\n\n\n<p>\u3053\u306e\u5f0f\u3092\u691c\u8a3c\u3059\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST14.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u3059\u308b\u3068\u3001\u4e0a\u56f3\u306e\u3088\u3046\u306b\u304d\u308c\u3044\u306b\u76f4\u7dda\u306b\u4e57\u308b\u4e8b\u304c\u5224\u308b\u3002<\/p>\n\n\n\n<p>\u73fe\u5728\u3001HSP\u306e\u6e29\u5ea6\u4f9d\u5b58\u6027\u306f\u3001<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/den-theory\">\u71b1\u81a8\u5f35\u7387<\/a>\u304b\u3089\u7b97\u51fa\u3055\u308c\u308b\u3002<\/p>\n\n\n\n<p>d\/dT \u03b4D = -1.25\u03b1 \u03b4D<br>d\/dT \u03b4P = &#8211; \u03b1 \u03b4P\/2<br>d\/dT \u03b4H = -(1.22 x 10<sup>-3 <\/sup>+ \u03b1\/2)\u03b4H<br>\u03b1 = a*(1-T\/Tc)<sup>m<\/sup><\/p>\n\n\n\n<p>\u6b21\u5143\u304c\u7570\u306a\u308b\u306e\u3067\u3001\u3053\u306e\u5f0f\u306f\u6b63\u3057\u304f\u306a\u3044\u3068\u601d\u3063\u3066\u3044\u305f\u304c\u3001\u8868\u9762\u5f35\u529b\u3084\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\u306e\u6e29\u5ea6\u5fae\u5206\u306f\u3001\u5206\u5b50\u4f53\u7a4d\u306e\u6e29\u5ea6\u5fae\u5206\uff1d\u71b1\u81a8\u5f35\u4fc2\u6570\u3068\u95a2\u4fc2\u304c\u3042\u308b\u3068\u8003\u3048\u308b\u6839\u62e0\u304c\u3001\u3053\u306eBeerbower\u306e\u5f0f\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<p>\u3053\u308c\u3089\u306e\u77e5\u898b\u3092\u57fa\u306b\u3001\u8868\u9762\u5f35\u529b\u3092\u30cf\u30f3\u30bb\u30f3\u30fb\u30bf\u30a4\u30d7\u306b\u5206\u5272\u3059\u308bQSPR\u5f0f\u3092\u69cb\u7bc9\u3057\u3066\u307f\u305f\u3002<br>Butyronitrile \u306e\u4f8b\u3067\u306f\u4e0b\u56f3\u306e\u3088\u3046\u306a\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST15.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>n-Butanol \u306e\u4f8b\u3067\u306f\u6b21\u306e\u3088\u3046\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/NewST16.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p>\u7dd1\u8272: ST-dis, \u5206\u6563\u9805<br>\u7d2b: ST-pol, \u5206\u6975\u9805<br>\u6c34\u8272: ST-hdo, \u6c34\u7d20\u7d50\u5408\u3001\u30c9\u30ca\u30fc\u6027<br>\u30aa\u30ec\u30f3\u30b8: ST-hac, \u6c34\u7d20\u7d50\u5408\u3001\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6027<\/p>\n\n\n\n<p>\u5168\u8868\u9762\u5f35\u529b\uff08\u8d64\uff09\u306f\u305d\u308c\u3089\u3092\u8db3\u3057\u305f\u3082\u306e\u306b\u306a\u308b\u3002<\/p>\n\n\n\n<p>ST-tot= ST-dis + ST-pol + ST-hdo + ST-hac<\/p>\n\n\n\n<p>\u8868\u9762\u5f35\u529b\u306e\u6c34\u7d20\u7d50\u5408\u9805\u306f\u30a2\u30eb\u30b3\u30fc\u30eb\u3067\u3042\u3063\u3066\u3082\u975e\u5e38\u306b\u5c0f\u3055\u304f\u306a\u308b\u3002\u3053\u308c\u306f\u89aa\u6c34\u6027\u201d\u3001\u201c\u89aa\u6cb9\u6027\u201d\u3082\u6c34\u7d20\u7d50\u5408\u3082\u8868\u9762\u5f35\u529b\u306b\u306f\u95a2\u4fc2\u306a\u3044\u306e\u3067\u5f53\u305f\u308a\u524d\u304b\u3082\u3057\u308c\u306a\u3044\u304c\u3001\u30cf\u30f3\u30bb\u30f3\u306e\u6eb6\u89e3\u5ea6\u30d1\u30e9\u30e1\u30fc\u30bf\u3068\u306f\u5927\u304d\u306a\u9055\u3044\u3067\u3042\u308b\u3002<\/p>\n\n\n\n<p><s>\u3053\u306e\u8868\u9762\u5f35\u529b\u306e\uff14\u6b21\u5143\u5206\u5272\u30eb\u30fc\u30c1\u30f3\u3001\u65b0\u898f\u8a08\u7b97\u65b9\u6cd5\u306b\u3064\u3044\u3066\u306f\u3001\u5c06\u6765\u306fHSPiP\u306b\u642d\u8f09\u3055\u308c\u308b\u304b\u3082\u3057\u308c\u306a\u3044\u3002\uff08\u5148\u306b\u3069\u3046\u3057\u3066\u3082\u4f7f\u3044\u305f\u3044\u5834\u5408\u306b\u306f\u3001HSPiP\u30e6\u30fc\u30b6\u30fc\u3067\u3042\u308c\u3070URL\u3092\u304a\u6559\u3048\u3057\u307e\u3059\u306e\u3067\u9023\u7d61\u3092\u3044\u305f\u3060\u3051\u308c\u3070\u3068\u601d\u3044\u307e\u3059\u3002\uff09<\/s><\/p>\n\n\n\n<p>\u3061\u306a\u307f\u306b Macleod \u2013 Sudgen \u306e\u30d1\u30e9\u30b3\u30fc\u30eb\u306e\u5024\u306f\u30e2\u30eb\u5c48\u6298[RD]\u3068\u76f8\u95a2\u304c\u3042\u308b\u3002<\/p>\n\n\n\n<p>\u03b3= (P*(\u03c1-d)\/M)<sup>4<\/sup><br>P: parachor, \u03c1: density of liquid, d: density of Gas, M: molecular weight<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/www.pirika.com\/Chemistry\/JP\/TCPE\/images\/RI2V11.jpg\" alt=\"NewST01\"\/><\/figure>\n\n\n\n<p><br>\u8a73\u3057\u3044\u3053\u3068\u306f<a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/refractiveindex2\">\u5c48\u6298\u7387\u306e\u63a8\u7b97\u305d\u306e\uff12<\/a>\u3092\u53c2\u7167\u3057\u3066\u9802\u304d\u305f\u3044\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\">\u7269\u6027\u5316\u5b66\u30c8\u30c3\u30d7\u30da\u30fc\u30b8<\/a><\/h2>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<p>Copyright pirika.com since 1999-<br>Mail: yamahiro<mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-bright-red-color\">X<\/mark>pirika.com (<mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-bright-red-color\">X<\/mark>\u3092@\u306b\u7f6e\u304d\u63db\u3048\u3066\u304f\u3060\u3055\u3044) <br>\u30e1\u30fc\u30eb\u306e\u4ef6\u540d\u306f[pirika]\u3067\u59cb\u3081\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>2013.8.16 \u7269\u6027\u5316\u5b66\u30c8\u30c3\u30d7\u30da\u30fc\u30b8 \u8868\u9762\u5f35\u529b\u306e\u63a8\u7b97\u6cd5\u3082\u53c2\u7167\u3057\u3066\u304f\u3060\u3055\u3044\u3002\u6b21\u4e16\u4ee3HSP\u6280\u8853\u3001HSP\u3068\u8868\u9762\u5f35\u529b\u3092\u53c2\u7167\u3057\u3066\u304f\u3060\u3055\u3044\u3002 \u8868\u9762\u5f35\u529b\uff08\u3072\u3087\u3046\u3081\u3093\u3061\u3087\u3046\u308a\u3087\u304f\u3001\u82f1\u8a9e: surface tension\uff09\u306f\u3001\u8868\u9762\u3092\u3067 &hellip; <a href=\"https:\/\/www.pirika.com\/wp\/chemistry-at-pirika-com\/chemistry\/tcpe\/surfacetension2\" class=\"more-link\"><span class=\"screen-reader-text\">&#8220;\u8868\u9762\u5f35\u529b\u306e\u7406\u89e3\u306e\u305f\u3081\u306b&#8221; \u306e<\/span>\u7d9a\u304d\u3092\u8aad\u3080<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":417,"menu_order":19,"comment_status":"open","ping_status":"closed","template":"","meta":{"_locale":"ja","_original_post":"https:\/\/www.pirika.com\/wp\/%e8%a1%a8%e9%9d%a2%e5%bc%b5%e5%8a%9b%e3%81%ae%e7%90%86%e8%a7%a3%e3%81%ae%e3%81%9f%e3%82%81%e3%81%ab","footnotes":""},"class_list":["post-4394","page","type-page","status-publish","hentry","ja"],"jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/pages\/4394","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/comments?post=4394"}],"version-history":[{"count":9,"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/pages\/4394\/revisions"}],"predecessor-version":[{"id":7745,"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/pages\/4394\/revisions\/7745"}],"up":[{"embeddable":true,"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/pages\/417"}],"wp:attachment":[{"href":"https:\/\/www.pirika.com\/wp\/wp-json\/wp\/v2\/media?parent=4394"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}